There are numerous features within the software that tie to a users facebook accounts.
Highlights of facebook specific features:
You can find more specifics about the Social Connect addon here within the support wiki
You can find out more about the Social Connect addon with that addons support wiki page here
You can install and enable both the Social Connect and Sharing addons within the following admin tool:
ADDONS > MANAGE ADDONS
Doing so would create the following sections in the admin tool:
ADDONS > SOCIAL CONNECT ADDONS > SHARING
The only configuration for the social connect addon is to fill in the necessary information provided by facebook within the following admin tool page:
ADDONS > SOCIAL CONNECT > SETTINGS
The steps to setup facebook's login feature is here in the support wiki.
Within the following admin tool you would set which social media sites to you wish to allow your users to share listings to:
ADDONS > SHARING > SETTINGS
One of which is facebook