After clicking the edit button next to our chosen extra not in current use you'll see a page like this one:
Within that screenshot you'll see:
We already have a both body and page template attached to that page by default. But in this example we are going to use the default page template but assign our custom extra page body template to user for the body to display our custom content. To assign our brand_new_extra_page.tpl template for use on this extra page click the edit attachment button next to the current body template attached. By default that should be additional_page.tpl template. We chose extra page 15 for this tutorial and clicking edit attachments leads you to the page that allows you to attach templates to pages. You can alternatively get to this same "page to template attachment" page through the DESIGN > PAGE ATTACHMENT admin tool also.
Within the above screenshot you'll see:
Now to test go to the url in 2 above to make sure the extra page appears as expected.